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Sodium sulfite (sodium sulphite) is the inorganic compound with the chemical formula Na 2 SO 3.A white, water-soluble solid, it is used commercially as an antioxidant and preservative.
Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO 3.Sodium bisulfite is not a real compound, [2] but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions.
Solutions of bisulfite are typically prepared by treatment of sulfur dioxide with aqueous base: [3]. SO 2 + OH − → HSO − 3. HSO − 3 is the conjugate base of sulfurous acid, (H 2 SO 3).
Sulfurous acid is commonly known to not exist in its free state, and due to this, it is stated in textbooks that it cannot be isolated in the water-free form. [4] However, the molecule has been detected in the gas phase in 1988 by the dissociative ionization of diethyl sulfite. [5]
Sodium metabisulfite, despite not being flammable, decomposes in 150 °C of heat releasing toxic gasses when decomposed. It is corrosive when dissolved in water. Some people who are sulfite sensitive may experience an allergic reaction to sodium meta bisulfite, sometimes severe, resulting in labeling requirements for food safety. [20]
Sodium sulfide is a chemical compound with the formula Na 2 S, or more commonly its hydrate Na 2 S·9H 2 O.Both the anhydrous and the hydrated salts in pure crystalline form are colorless solids, although technical grades of sodium sulfide are generally yellow to brick red owing to the presence of polysulfides and commonly supplied as a crystalline mass, in flake form, or as a fused solid.
The structure of the sulfite anion Sulfite is a ligand in coordination chemistry.The structure of Co(ethylenediamine) 2 (SO 3)N 3.[4]The structure of the sulfite anion can be described with three equivalent resonance structures.
Sodium bisulfate, also known as sodium hydrogen sulfate, [a] is the sodium salt of the bisulfate anion, with the molecular formula NaHSO 4.Sodium bisulfate is an acid salt formed by partial neutralization of sulfuric acid by an equivalent of sodium base, typically in the form of either sodium hydroxide (lye) or sodium chloride (table salt).