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In thermodynamics, the Helmholtz free energy (or Helmholtz energy) is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature . The change in the Helmholtz energy during a process is equal to the maximum amount of work that the system can perform in a thermodynamic process ...
Properties of isolated, closed, and open thermodynamic systems in exchanging energy and matter. A thermodynamic system is a body of matter and/or radiation separate from its surroundings that can be studied using the laws of thermodynamics. Thermodynamic systems can be passive and active according to internal processes.
Matter or energy that pass across the boundary so as to effect a change in the internal energy of the system need to be accounted for in the energy balance equation. The volume contained by the walls can be the region surrounding a single atom resonating energy, such as Max Planck defined in 1900; it can be a body of steam or air in a steam ...
Classical mechanics is the branch of physics used to describe the motion of macroscopic objects. [1] It is the most familiar of the theories of physics. The concepts it covers, such as mass, acceleration, and force, are commonly used and known. [2]
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
For isolated systems, no energy is provided by the surroundings and the second law requires that the entropy of the system alone must increase: ΔS > 0. Examples of spontaneous physical processes in isolated systems include the following: 1) Heat can be transferred from a region of higher temperature to a lower temperature (but not the reverse).
In thermodynamics, dissipation is the result of an irreversible process that affects a thermodynamic system.In a dissipative process, energy (internal, bulk flow kinetic, or system potential) transforms from an initial form to a final form, where the capacity of the final form to do thermodynamic work is less than that of the initial form.
In thermodynamics, entropy is related to the amount of energy of a system that can be converted into mechanical work in a concrete process. [17] In quantum mechanics, this translates to the ability to measure and manipulate the system based on the information gathered by measurement.