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The second law of thermodynamics may be expressed in many specific ways, [25] the most prominent classical statements [26] being the statement by Rudolf Clausius (1854), the statement by Lord Kelvin (1851), and the statement in axiomatic thermodynamics by Constantin Carathéodory (1909). These statements cast the law in general physical terms ...
The laws of thermodynamics are the result of progress made in this field over the nineteenth and early twentieth centuries. The first established thermodynamic principle, which eventually became the second law of thermodynamics, was formulated by Sadi Carnot in 1824 in his book Reflections on the Motive Power of Fire.
The zeroth law was not initially recognized as a separate law of thermodynamics, as its basis in thermodynamical equilibrium was implied in the other laws. The first, second, and third laws had been explicitly stated already, and found common acceptance in the physics community before the importance of the zeroth law for the definition of ...
The zeroth law is of importance in thermometry, because it implies the existence of temperature scales. In practice, C is a thermometer, and the zeroth law says that systems that are in thermodynamic equilibrium with each other have the same temperature. The law was actually the last of the laws to be formulated. First law of thermodynamics
The Clausius inequality is a consequence of applying the second law of thermodynamics at each infinitesimal stage of heat transfer. The Clausius statement states that it is impossible to construct a device whose sole effect is the transfer of heat from a cool reservoir to a hot reservoir. [ 3 ]
The second law of thermodynamics is statistical in nature, and therefore its reliability arises from the huge number of particles present in macroscopic systems. It is not impossible, in principle, for all 6 × 10 23 atoms in a mole of a gas to spontaneously migrate to one half of a container; it is only fantastically unlikely—so unlikely ...
John Earman and John D. Norton have argued that Szilárd and Landauer's explanations of Maxwell's demon begin by assuming that the second law of thermodynamics cannot be violated by the demon, and derive further properties of the demon from this assumption, including the necessity of consuming energy when erasing information, etc. [15] [16] It ...
According to the laws of thermodynamics, any hot object transfers heat to its cooler surroundings, until everything is at the same temperature. For two objects at the same temperature as much heat flows from one body as flows from the other, and the net effect is no change. If the universe were infinitely old, there must have been enough time ...