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Selenium is found in metal sulfide ores, where it substitutes for sulfur. Commercially, selenium is produced as a byproduct in the refining of these ores. Minerals that are pure selenide or selenate compounds are rare. The chief commercial uses for selenium today are glassmaking and pigments. Selenium is a semiconductor and is used in photocells.
The sulfoxide in sulfur chemistry is represented in selenium chemistry by the selenoxides (formula RSe(O)R), which are intermediates in organic synthesis, as illustrated by the selenoxide elimination reaction. Consistent with trends indicated by the double bond rule, selenoketones, R(C=Se)R, and selenaldehydes, R(C=Se)H, are rarely observed.
Simplest is the material selenium sulfide, which has medicinal properties. It adopt the diverse structures of elemental sulfur but with some S atoms replaced by Se. Other inorganic selenide sulfide compounds occur as minerals and as pigments. One example is antimony selenosulfide.
In organic chemistry, a sulfoxide, also called a sulphoxide, is an organosulfur compound containing a sulfinyl (>SO) functional group attached to two carbon atoms. It is a polar functional group. Sulfoxides are oxidized derivatives of sulfides .
The simplest sulfoxide, dimethyl sulfoxide, is a common solvent; a common sulfone is sulfolane. Sulfonic acids are used in many detergents. Compounds with carbon–sulfur multiple bonds are uncommon, an exception being carbon disulfide, a volatile colorless liquid that is structurally similar to carbon dioxide.
Selenium in these reactions is almost always stereogenic, and the effect of epimerization at selenium (which is acid-catalyzed and occurs readily) on the elimination reaction is nearly unknown. In one example, separation and warming of selenoxides 1 and 2 revealed that 2 decomposes at 0 °C, while 1 , which presumably has more difficulty ...
[1] [2] [3] Selenium belongs with oxygen and sulfur to the group 16 elements or chalcogens, and similarities in chemistry are to be expected. Organoselenium compounds are found at trace levels in ambient waters, soils and sediments. [4] Selenium can exist with oxidation state −2, +2, +4, +6. Se(II) is the dominant form in organoselenium ...
Selenium sulfide can refer to either of the following: Selenium disulfide, SeS 2; Selenium hexasulfide, Se 2 S 6 This page was last edited on 27 January ...