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The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system: that is, a measure of the system's overall polarity. ...
Note that the dipole moments drawn in this diagram represent the shift of the valence electrons as the origin of the charge, which is opposite the direction of the actual electric dipole moment. The bond dipole moment [5] uses the idea of electric dipole moment to measure the polarity of a chemical bond within a molecule. It occurs whenever ...
Polarizability increases down on columns of the periodic table. [9] Likewise, larger molecules are generally more polarizable than smaller ones. Water is a very polar molecule, but alkanes and other hydrophobic molecules are more polarizable. Water with its permanent dipole is less likely to change shape due to an external electric field.
Transition dipole moment, the electrical dipole moment in quantum mechanics; Molecular dipole moment, the electric dipole moment of a molecule. Bond dipole moment, the measure of polarity of a chemical bond; Electron electric dipole moment, the measure of the charge distribution within an electron; Magnetic dipole moment, the measure of the ...
The electron's electric dipole moment (EDM) must be collinear with the direction of the electron's magnetic moment (spin). [1] Within the Standard Model , such a dipole is predicted to be non-zero but very small, at most 10 −38 e ⋅cm , [ 2 ] where e stands for the elementary charge .
The electric displacement field "D" is defined as +, where is the vacuum permittivity (also called permittivity of free space), E is the electric field, and P is the (macroscopic) density of the permanent and induced electric dipole moments in the material, called the polarization density.
In organic chemistry, a dipolar compound or simply dipole is an electrically neutral molecule carrying a positive and a negative charge in at least one canonical description. In most dipolar compounds the charges are delocalized . [ 1 ]
In contrast to NH 3, NF 3 has a much lower dipole moment of 0.234 D. Fluorine is more electronegative than nitrogen and the polarity of the N-F bonds is opposite to that of the N-H bonds in ammonia, so that the dipole due to the lone pair opposes the N-F bond dipoles, resulting in a low molecular dipole moment. [6]