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The IUPAC definition [1] of relative atomic mass is: An atomic weight (relative atomic mass) of an element from a specified source is the ratio of the average mass per atom of the element to 1/12 of the mass of an atom of 12 C. The definition deliberately specifies "An atomic weight ...", as an element will have different relative atomic masses ...
As such, relative atomic mass and standard atomic weight often differ numerically from the relative isotopic mass. The atomic mass (relative isotopic mass) is defined as the mass of a single atom, which can only be one isotope (nuclide) at a time, and is not an abundance-weighted average, as in the case of relative atomic mass/atomic weight ...
The molar mass of atoms of an element is given by the relative atomic mass of the element multiplied by the molar mass constant, M u ≈ 1.000 000 × 10 −3 kg/mol ≈ 1 g/mol. For normal samples from Earth with typical isotope composition, the atomic weight can be approximated by the standard atomic weight [ 2 ] or the conventional atomic weight.
Equations Mass number: A = (Relative) atomic mass = Mass number = Sum of protons and neutrons; ... Equations Breit-Wigner formula:
The molar mass constant, usually denoted by M u, is a physical constant defined as one twelfth of the molar mass of carbon-12: M u = M(12 C)/12. [1] The molar mass of an element or compound is its relative atomic mass (atomic weight) or relative molecular mass (molecular weight or formula weight) multiplied by the molar mass constant.
Relative atomic and molecular masses as defined are dimensionless. Molar masses when expressed in g/mol have almost identical numerical values as relative atomic and molecular masses. For example, the molar mass and molecular mass of methane, whose molecular formula is CH 4, are calculated respectively as follows:
The electron relative atomic mass also enters into the calculation of all other relative atomic masses. By convention, relative atomic masses are quoted for neutral atoms, but the actual measurements are made on positive ions, either in a mass spectrometer or a Penning trap. Hence the mass of the electrons must be added back on to the measured ...
The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the atomic weight listed for the element in the periodic table. The abundance of an isotope varies from planet to planet, and even from place to place on the Earth, but remains relatively constant in time (on a short-term scale).