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Strictly speaking, the bulk modulus is a thermodynamic quantity, and in order to specify a bulk modulus it is necessary to specify how the pressure varies during compression: constant- temperature (isothermal ), constant- entropy (isentropic ), and other variations are possible. Such distinctions are especially relevant for gases.
Thermodynamics. In thermodynamics and fluid mechanics, the compressibility (also known as the coefficient of compressibility[1] or, if the temperature is held constant, the isothermal compressibility[2]) is a measure of the instantaneous relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.
The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance). As a result the equation is able to model the phase ...
Gassmann's equation. Gassmann's equations are a set of two equations describing the isotropic elastic constants of an ensemble consisting of an isotropic, homogeneous porous medium with a fully connected pore space, saturated by a compressible fluid at pressure equilibrium. First published in German [1] by Fritz Gassmann, the original work was ...
Volume viscosity. Volume viscosity (also called bulk viscosity, or second viscosity or, dilatational viscosity) is a material property relevant for characterizing fluid flow. Common symbols are or . It has dimensions (mass / (length × time)), and the corresponding SI unit is the pascal -second (Pa·s).
Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant. Therefore, when the volume is halved, the pressure is doubled; and if the volume is doubled, the pressure is halved.
The difference relation allows one to obtain the heat capacity for solids at constant volume which is not readily measured in terms of quantities that are more easily measured. The ratio relation allows one to express the isentropic compressibility in terms of the heat capacity ratio.
Some formulations for the Grüneisen parameter include: = = = = = ( ) where V is volume, and are the principal (i.e. per-mass) heat capacities at constant pressure and volume, E is energy, S is entropy, α is the volume thermal expansion coefficient, and are the adiabatic and isothermal bulk moduli, is the speed of sound in the medium ...