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The contact process is a method of producing sulfuric acid in the high concentrations needed for industrial processes. Platinum was originally used as the catalyst for this reaction; however, because it is susceptible to reacting with arsenic impurities in the sulfur feedstock, vanadium(V) oxide (V 2 O 5) has since been preferred.
Vanadium(V) oxide serves the crucial purpose of catalysing the mildly exothermic oxidation of sulfur dioxide to sulfur trioxide by air in the contact process: 2 SO 2 + O 2 ⇌ 2 SO 3. The discovery of this simple reaction, for which V 2 O 5 is the most effective catalyst, allowed sulfuric acid to become the cheap commodity chemical it is today.
Vanadium(V) oxide is a catalyst in the contact process for producing sulfuric acid. Vanadium compounds are used extensively as catalysts; [83] Vanadium pentoxide V 2 O 5, is used as a catalyst in manufacturing sulfuric acid by the contact process [84] In this process sulfur dioxide (SO 2) is oxidized to the trioxide (SO
Vanadium oxide mainly refers to: Vanadium(II) oxide (vanadium monoxide), VO; Vanadium(III) oxide (vanadium sesquioxide or trioxide), V 2 O 3; Vanadium(IV) oxide (vanadium dioxide), VO 2; Vanadium(V) oxide (vanadium pentoxide), V 2 O 5; Various other distinct phases include: Phases with the general formula V n O 2n+1 exist between V 2 O 5 and VO 2.
Claus process: vanadium pentoxide (heterogeneous) sulfur: remediation of byproduct of oil refinery: methane, ammonia: Andrussow process: platinum (heterogeneous) hydrogen cyanide: basic chemicals, gold mining extractant ethylene: epoxidation: mixed Ag oxides (heterogeneous) ethylene oxide: basic chemicals, surfactants cyclohexane: K-A process ...
Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements , niobium and tantalum , are somewhat more limited to the +5 oxidation state. [ 1 ]
The semiconducting form is rich in vanadium pentoxide. [3] [5] At high temperatures or when there is a lower availability of oxygen, refractory oxides—vanadium dioxide and vanadium trioxide—form. These more reduced forms of vanadium do not promote corrosion. However, at conditions most common for burning, vanadium pentoxide gets formed.
The lead chamber process was an industrial method used to produce sulfuric acid in large quantities. It has been largely supplanted by the contact process.. In 1746 in Birmingham, England, John Roebuck began producing sulfuric acid in lead-lined chambers, which were stronger and less expensive and could be made much larger than the glass containers that had been used previously.