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Raman spectroscopy (/ ˈrɑːmən /) (named after physicist C. V. Raman) is a spectroscopic technique typically used to determine vibrational modes of molecules, although rotational and other low-frequency modes of systems may also be observed. [1] Raman spectroscopy is commonly used in chemistry to provide a structural fingerprint by which ...
v. t. e. In chemistry and physics, Raman scattering or the Raman effect (/ ˈrɑːmən /) is the inelastic scattering of photons by matter, meaning that there is both an exchange of energy and a change in the light's direction. Typically this effect involves vibrational energy being gained by a molecule as incident photons from a visible laser ...
The basic principle of Raman optical activity is that there is interference between light waves scattered by the polarizability and optical activity tensors of a chiral molecule, which leads to a difference between the intensities of the right- and left-handed circularly polarised scattered beams. The spectrum of intensity differences recorded ...
Coherent anti-Stokes Raman spectroscopy, also called Coherent anti-Stokes Raman scattering spectroscopy (CARS), is a form of spectroscopy used primarily in chemistry, physics and related fields. It is sensitive to the same vibrational signatures of molecules as seen in Raman spectroscopy, typically the nuclear vibrations of chemical bonds.
Coherent anti-Stokes Raman spectroscopy (CARS) is a non- linear process in which the energy difference of a pair of incoming photons matches the energy of the vibrational mode of a molecular bond of interest. This phonon population is coherently probed by a third photon and anti- Stokes radiation is emitted. Polarization-dependent artifacts
The ratio of the peak intensity of the parallel and perpendicular component is known as the depolarization ratio (ρ), defined in equation 1. [3] For example, a spectral band with a peak of intensity 10 units when the polarizers are parallel, and an intensity 1 unit when the polarizers are perpendicular, would have a depolarization ratio of 1/ ...
Raman amplification / ˈrɑːmən / [1] is based on the stimulated Raman scattering (SRS) phenomenon, when a lower frequency 'signal' photon induces the inelastic scattering of a higher-frequency 'pump' photon in an optical medium in the nonlinear regime. As a result of this, another 'signal' photon is produced, with the surplus energy ...
Resonance Raman spectroscopy (RR spectroscopy or RRS) is a variant of Raman spectroscopy in which the incident photon energy is close in energy to an electronic transition of a compound or material under examination. [1] This similarity in energy (resonance) leads to greatly increased intensity of the Raman scattering of certain vibrational ...