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Exposure to hexavalent chromium can cause irritation and problems in the respiratory tract, stomach, and small intestine. It is linked to several cancers, such as lung cancer, oral cancer, and intestinal cancer. [11] During floods, the chromium contaminated groundwater would flood into local Garfield residences and businesses.
Hydrated chromium(III) sulfate, Cr 2 (SO 4) 3 ·18H 2 O, (CAS #13520-66-6) is a violet solid that readily dissolves in water to give the metal aquo complex, [Cr(H 2 O) 6] 3+. The formula of this compound can be written more descriptively as [Cr(H 2 O) 6 ] 2 (SO 4 ) 3 ·6H 2 O. Six of the eighteen water molecules in this formula unit are water ...
Average hexavalent chromium levels in Hinkley were recorded as 1.19 parts-per-billion (ppb), with an estimated peak of 20 ppb. Based on the PG&E Background Study, the PG&E Topock Compressor Station averaged 7.8 ppb and peaked at 31.8 ppb. [33] The proposed California health goal for hexavalent chromium was 0.02 ppb in 2011. [34]
Hexavalent chromium (chromium(VI), Cr(VI), chromium 6) is any chemical compound that contains the element chromium in the +6 oxidation state (thus hexavalent). [1] It has been identified as carcinogenic, which is of concern since approximately 136,000 tonnes (150,000 tons) of hexavalent chromium were produced in 1985. [ 2 ]
Chromium compounds are compounds containing the element chromium (Cr). Chromium is a member of group 6 of the transition metals. The +3 and +6 states occur most commonly within chromium compounds, followed by +2; charges of +1, +4 and +5 for chromium are rare, but do nevertheless occasionally exist. [3] [4]
Chromium toxicity refers to any poisonous toxic effect in an organism or cell that results from exposure to specific forms of chromium—especially hexavalent chromium. [1] Hexavalent chromium and its compounds are toxic when inhaled or ingested. Trivalent chromium is a trace mineral that is essential to human nutrition.
Hexavalent chromium compounds (including chromium trioxide, chromic acids, chromates, chlorochromates) are toxic and carcinogenic. Chromium trioxide and chromic acids are strong oxidizers and may react violently if mixed with easily oxidizable organic substances. Chromic acid burns are treated with a dilute sodium thiosulfate solution. [18]
As hexavalent chromium compounds are prohibited for use in the EU based on ROHS regulations and are toxic and carcinogenic, solutions based on molybdate are proposed as a replacement (e.g. molybdate 30-100g/ boric acid 10-18 g/manganese sulfate 0.5 - 5 g/1 liter of water, 0.1 - 20 A/dm2, 0.1–15 minutes). [32] [33]