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For a reversible reaction, the equilibrium constant can be measured at a variety of temperatures. This data can be plotted on a graph with ln K eq on the y-axis and 1 / T on the x axis. The data should have a linear relationship, the equation for which can be found by fitting the data using the linear form of the Van 't Hoff equation
This equation can be used to calculate the value of log K at a temperature, T 2, knowing the value at temperature T 1. The van 't Hoff equation also shows that, for an exothermic reaction ( Δ H < 0 {\displaystyle \Delta H<0} ), when temperature increases K decreases and when temperature decreases K increases, in accordance with Le Chatelier's ...
log 10 β values between about 2 and 11 can be measured directly by potentiometric titration using a glass electrode. This enormous range of stability constant values (ca. 100 to 10 11) is possible because of the logarithmic response of the electrode. The limitations arise because the Nernst equation breaks down at very low or very high pH.
Measure for the ease with which an object resists conduction of heat K/W L −2 M −1 T 3 Θ: extensive Thermal resistivity R λ: Measure for the ease with which a material resists conduction of heat K⋅m/W L −1 M −1 T 3 Θ: intensive Viscosity: η: The measure of the internal friction in a fluid Pa⋅s L −1 M T −1: intensive, scalar ...
The value of a physical quantity Z is expressed as the product of a numerical value {Z} (a pure number) and a unit [Z]: = {} [] For example, let be "2 metres"; then, {} = is the numerical value and [] = is the unit. Conversely, the numerical value expressed in an arbitrary unit can be obtained as:
As there are many units of mass and volume covering many different magnitudes there are a large number of units for mass density in use. The SI unit of kilogram per cubic metre (kg/m 3) and the cgs unit of gram per cubic centimetre (g/cm 3) are probably the most commonly used units for density.
The density of water is approximately 1g/mL whether you consider a drop of water or a swimming pool, but the mass is different in the two cases. Dividing one extensive property by another extensive property gives an intensive property—for example: mass (extensive) divided by volume (extensive) gives density (intensive).
In SI units, the density of water is (approximately) 1000 kg/m 3 or 1 g/cm 3, which makes relative density calculations particularly convenient: the density of the object only needs to be divided by 1000 or 1, depending on the units. The relative density of gases is often measured with respect to dry air at a temperature of 20 °C and a ...