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  2. Electron density - Wikipedia

    en.wikipedia.org/wiki/Electron_density

    Electron density calculated for aniline, high density values indicate atom positions, intermediate density values emphasize bonding, low values provide information on a molecule's shape and size. where P is the density matrix. Electron densities are often rendered in terms of an isosurface (an isodensity surface) with the size and shape of the ...

  3. Atomic orbital - Wikipedia

    en.wikipedia.org/wiki/Atomic_orbital

    The repeating periodicity of blocks of 2, 6, 10, and 14 elements within sections of periodic table arises naturally from total number of electrons that occupy a complete set of s, p, d, and f orbitals, respectively, though for higher values of quantum number n, particularly when the atom bears a positive charge, energies of certain sub-shells ...

  4. Oxygen - Wikipedia

    en.wikipedia.org/wiki/Oxygen

    Orbital diagram, after Barrett (2002), [33] showing the participating atomic orbitals from each oxygen atom, the molecular orbitals that result from their overlap, and the aufbau filling of the orbitals with the 12 electrons, 6 from each O atom, beginning from the lowest-energy orbitals, and resulting in covalent double-bond character from ...

  5. Electronic band structure - Wikipedia

    en.wikipedia.org/wiki/Electronic_band_structure

    The second model starts from the opposite limit, in which the electrons are tightly bound to individual atoms. The electrons of a single, isolated atom occupy atomic orbitals with discrete energy levels. If two atoms come close enough so that their atomic orbitals overlap, the electrons can tunnel between the atoms.

  6. Electronegativity - Wikipedia

    en.wikipedia.org/wiki/Electronegativity

    Electrostatic potential map of a water molecule, where the oxygen atom has a more negative charge (red) than the positive (blue) hydrogen atoms. Electronegativity, symbolized as χ, is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond. [1]

  7. Electron shell - Wikipedia

    en.wikipedia.org/wiki/Electron_shell

    In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus.The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus.

  8. Inductive effect - Wikipedia

    en.wikipedia.org/wiki/Inductive_effect

    In acids, the electron-releasing inductive effect of the alkyl group increases the electron density on oxygen and thus hinders the breaking of the O-H bond, which consequently reduces the ionization. Due to its greater ionization, formic acid ( pK a =3.74 ) is stronger than acetic acid ( pK a =4.76 ).

  9. Molecular orbital - Wikipedia

    en.wikipedia.org/wiki/Molecular_orbital

    In an isolated atom, the orbital electrons' location is determined by functions called atomic orbitals. When multiple atoms combine chemically into a molecule by forming a valence chemical bond, the electrons' locations are determined by the molecule as a whole, so the atomic orbitals combine to form molecular orbitals. The electrons from the ...