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Phosphorus pentabromide is a reactive, yellow solid of formula P Br 5, which has the structure [PBr 4] + Br − (tetrabromophosphonium bromide) in the solid state but in the vapor phase is completely dissociated to PBr 3 and Br 2.
The propensity for any two substances to form a solid solution is a complicated matter involving the chemical, crystallographic, and quantum properties of the substances in question. Substitutional solid solutions, in accordance with the Hume-Rothery rules, may form if the solute and solvent have: Similar atomic radii (15% or less difference)
Hume-Rothery rules, named after William Hume-Rothery, are a set of basic rules that describe the conditions under which an element could dissolve in a metal, forming a solid solution. There are two sets of rules; one refers to substitutional solid solutions, and the other refers to interstitial solid solutions.
In metallurgy, solid solution strengthening is a type of alloying that can be used to improve the strength of a pure metal. [1] The technique works by adding atoms of one element (the alloying element) to the crystalline lattice of another element (the base metal), forming a solid solution .
A and B can also be the same metal with different valences, as is the case with magnetite, Fe 3 O 4 (as Fe 2+ Fe 3+ 2 O 2− 4), which is the most abundant member of the spinel group. [3] Spinels are grouped in series by the B cation. The group is named for spinel (MgAl 2 O 4), which was once known as "spinel ruby". [4] (Today the term ruby is ...
The term phase is sometimes used as a synonym for state of matter, but it is possible for a single compound to form different phases that are in the same state of matter. For example, ice is the solid state of water, but there are multiple phases of ice with different crystal structures, which are formed at different pressures and temperatures.
Nonmetals show more variability in their properties than do metals. [1] Metalloids are included here since they behave predominately as chemically weak nonmetals.. Physically, they nearly all exist as diatomic or monatomic gases, or polyatomic solids having more substantial (open-packed) forms and relatively small atomic radii, unlike metals, which are nearly all solid and close-packed, and ...
The resulting solid macrostructure from a eutectic reaction depends on a few factors, with the most important factor being how the two solid solutions nucleate and grow. The most common structure is a lamellar structure , but other possible structures include rodlike, globular, and acicular .