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A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The third term (the Hessian of V) evaluated in the minimum is a force derivative matrix F. In the harmonic approximation the Taylor series is ended after this term. The second term, containing first derivatives, is zero because it is evaluated in the minimum of V. The first term can be included in the zero of energy. Thus,
A simple harmonic oscillator is an oscillator that is neither driven nor damped.It consists of a mass m, which experiences a single force F, which pulls the mass in the direction of the point x = 0 and depends only on the position x of the mass and a constant k.
In chemistry, a chemical oscillator is a complex mixture of reacting chemical compounds in which the concentration of one or more components exhibits periodic changes. They are a class of reactions that serve as an example of non-equilibrium thermodynamics with far-from-equilibrium behavior.
Oscillation is the repetitive or periodic variation, typically in time, of some measure about a central value (often a point of equilibrium) or between two or more different states. Familiar examples of oscillation include a swinging pendulum and alternating current. Oscillations can be used in physics to approximate complex interactions, such ...
The Schrödinger equation for a particle in a spherically-symmetric three-dimensional harmonic oscillator can be solved explicitly by separation of variables. This procedure is analogous to the separation performed in the hydrogen-like atom problem, but with a different spherically symmetric potential V ( r ) = 1 2 μ ω 2 r 2 , {\displaystyle ...
A wave can be longitudinal where the oscillations are parallel (or antiparallel) to the propagation direction, or transverse where the oscillations are perpendicular to the propagation direction. These oscillations are characterized by a periodically time-varying displacement in the parallel or perpendicular direction, and so the instantaneous ...
The g-force or gravitational force equivalent is a mass-specific force (force per unit mass), expressed in units of standard gravity (symbol g or g 0, not to be confused with "g", the symbol for grams).