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Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension General heat/thermal capacity C = / J⋅K −1: ML 2 T −2 Θ −1: Heat capacity (isobaric)
The concepts of Hess's law can be expanded to include changes in entropy and in Gibbs free energy, since these are also state functions. The Bordwell thermodynamic cycle is an example of such an extension that takes advantage of easily measured equilibria and redox potentials to determine experimentally inaccessible Gibbs free energy values.
Hence, the main functional application of Gibbs energy from a thermodynamic database is its change in value during the formation of a compound from the standard-state elements, or for any standard chemical reaction (ΔG° form or ΔG° rx). The SI units of Gibbs energy are the same as for enthalpy (J/mol).
In other words, its potential energy is zero. Hence, all the energy possessed by the gas is the kinetic energy of the molecules, or atoms, of the gas. = This corresponds to the kinetic energy of n moles of a monoatomic gas having 3 degrees of freedom; x, y, z. The table here below gives this relationship for different amounts of a monoatomic gas.
By the principle of minimum energy, there are a number of other state functions which may be defined which have the dimensions of energy and which are minimized according to the second law under certain conditions other than constant entropy. These are called thermodynamic potentials. For each such potential, the relevant fundamental equation ...
A related term is the heat of combustion, which is the chemical energy released due to a combustion reaction and of interest in the study of fuels. Food is similar to hydrocarbon and carbohydrate fuels, and when it is oxidized, its energy release is similar (though assessed differently than for a hydrocarbon fuel — see food energy).
In chemistry, bond energy (BE) is one measure of the strength of a chemical bond. It is sometimes called the mean bond , bond enthalpy , average bond enthalpy , or bond strength . [ 1 ] [ 2 ] [ 3 ] IUPAC defines bond energy as the average value of the gas-phase bond-dissociation energy (usually at a temperature of 298.15 K) for all bonds of the ...
which relates the Gibbs energy to a chemical equilibrium constant, the van 't Hoff equation can be derived. [ 9 ] Since the change in a system's Gibbs energy is equal to the maximum amount of non-expansion work that the system can do in a process, the Gibbs-Helmholtz equation may be used to estimate how much non-expansion work can be done by a ...