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The most common Lewis bases are anions. The strength of Lewis basicity correlates with the pK a of the parent acid: acids with high pK a 's give good Lewis bases. As usual, a weaker acid has a stronger conjugate base. Examples of Lewis bases based on the general definition of electron pair donor include: simple anions, such as H − and F −
G. N. Lewis realized that water, ammonia, and other bases can form a bond with a proton due to the unshared pair of electrons that the bases possess. [3] In the Lewis theory , a base is an electron pair donor which can share a pair of electrons with an electron acceptor which is described as a Lewis acid. [ 4 ]
Bases are defined by the Brønsted–Lowry theory as chemical substances that can accept a proton, i.e., a hydrogen ion. In water this is equivalent to a hydronium ion). The Lewis theory instead defines a Base as an electron-pair donor. The Lewis definition is broader — all Brønsted–Lowry bases are also Lewis bases.
In the same year that Brønsted and Lowry published their theory, G. N. Lewis created an alternative theory of acid–base reactions. The Lewis theory is based on electronic structure. A Lewis base is a compound that can give an electron pair to a Lewis acid, a compound that can accept an electron pair.
HSAB is an acronym for "hard and soft (Lewis) acids and bases".HSAB is widely used in chemistry for explaining the stability of compounds, reaction mechanisms and pathways. It assigns the terms 'hard' or 'soft', and 'acid' or 'base' to chemical species.
In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base.It can be used to determine pH via titration.Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called the acid–base theories, for example, Brønsted–Lowry acid–base theory.
In chemistry a donor number (DN) is a quantitative measure of Lewis basicity.A donor number is defined as the negative enthalpy value for the 1:1 adduct formation between a Lewis base and the standard Lewis acid SbCl 5 (antimony pentachloride), in dilute solution in the noncoordinating solvent 1,2-dichloroethane with a zero DN.
Lewis successfully contributed to chemical thermodynamics, photochemistry, and isotope separation, and is also known for his concept of acids and bases. [8] Lewis also researched on relativity and quantum physics, and in 1926 he coined the term "photon" for the smallest unit of radiant energy. [9] [10]