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A perchlorate is a chemical compound containing the perchlorate ion, ClO − 4, the conjugate base of perchloric acid (ionic perchlorate). As counterions, there can be metal cations , quaternary ammonium cations or other ions, for example, nitronium cation ( NO + 2 ).
Magnesium perchlorate is a powerful oxidizing agent, with the formula Mg(ClO 4) 2. The salt is also a superior drying agent for gas analysis. Magnesium perchlorate decomposes at 250 °C. [2] The heat of formation is -568.90 kJ/mol. [3] The enthalpy of solution is quite high, so reactions are done in large amounts of water to dilute it.
Sodium perchlorate is the precursor to ammonium, potassium and lithium perchlorate salts, often taking advantage of their low solubility in water relative to NaClO 4 (209 g/(100 mL) at 25 °C). [6] It is used for denaturating proteins in biochemistry and in standard DNA extraction and hybridization reactions in molecular biology.
Rubidium perchlorate can be obtained through the careful heating of a rubidium chlorate solution, leading to a disproportionation reaction with the release of oxygen gas: [3] 2 RbClO 3 → RbClO 4 + RbCl + O 2. When heated, it decomposes into the chloride and oxygen: [4] RbClO 4 → RbCl + 2 O 2. It has two polymorphs.
Chloride cycle dealkalizers operate similar to sodium cycle cation water softeners. Like water softeners, dealkalizers contain ion-exchange resins that are regenerated with a concentrated salt solution - NaCl. In the case of a water softener, the cation exchange resin is exchanging sodium (the Na + ion of NaCl) for hardness minerals such as ...
Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions. Soft water also extends the lifetime of plumbing by reducing or eliminating scale build-up in pipes
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