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[9] [11] [12] [13] The crosslinking mechanism of the hydrophilic macromolecules are driven by covalent bonding, resulting in a physical- or chemical-type hydrogel. Physical hydrogels contain reversible matrices of hydrogen and non-covalent bonds, while chemical hydrogels are composed of irreversible matrices that are molecularly held together ...
Self-healing hydrogels are a specialized type of polymer hydrogel.A hydrogel is a macromolecular polymer gel constructed of a network of crosslinked polymer chains. Hydrogels are synthesized from hydrophilic monomers by either chain or step growth, along with a functional crosslinker to promote network formation.
A nanogel is a polymer-based, crosslinked hydrogel particle on the sub-micron scale. [1] [2] [3] These complex networks of polymers present a unique opportunity in the field of drug delivery at the intersection of nanoparticles and hydrogel synthesis.
In polymer chemistry "cross-linking" usually refers to the use of cross-links to promote a change in the polymers' physical properties. When "crosslinking" is used in the biological field, it refers to the use of a probe to link proteins together to check for protein–protein interactions, as well as other creative cross-linking methodologies.
Specifically, hydrogels can be designed to release drugs or other agents in response to physical characteristics of the environment like temperature and pH. [12] The responsiveness of hydrogels is a result of their molecular structure and polymer networks. [12] Hydrogel nanoparticles have a promising future in the drug delivery field.
Hydrogel fiber is a hydrogel made into a fibrous state, where its width is significantly smaller than its length. The hydrogel's specific surface area at fibrous form is larger than that of the bulk hydrogel, and its mechanical properties also changed accordingly. As a result of these changes, hydrogel fiber has a faster matter exchange rate ...
Poly(2-hydroxyethyl methacrylate) (pHEMA) is a polymer that forms a hydrogel in water. Poly (hydroxyethyl methacrylate) (PHEMA) hydrogel for intraocular lens (IOL) materials was synthesized by solution polymerization using 2-hydroxyethyl methacrylate as raw material, ammonium persulfate and sodium pyrosulfite (APS/SMBS) as catalyst, and triethyleneglycol dimethacrylate (TEGDMA) as cross ...
Gelatin, here in sheets for cooking, is a hydrogel. Peptide hydrogel formation shown by the inverted vial method. A hydrogel is a biphasic material, a mixture of porous and permeable solids and at least 10% of water or other interstitial fluid.