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A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules.
Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum. Ideal line shapes include Lorentzian , Gaussian and Voigt functions, whose parameters are the line position, maximum height and half-width. [ 1 ]
The ability of positronium to form both singlet and triplet states is described mathematically by saying that the product of two doublet representations (meaning the electron and positron, which are both spin-1/2 doublets) can be decomposed into the sum of an adjoint representation (the triplet or spin 1 state) and a trivial representation (the ...
There is disagreement in the literature for some line designations; for example, the Fraunhofer d line may refer to the cyan iron line at 466.814 nm, or alternatively to the yellow helium line (also labeled D 3) at 587.5618 nm. Similarly, there is ambiguity regarding the e line, since it can refer to the spectral lines of both iron (Fe) and ...
The sharp series limit is the same as the diffuse series limit. In the late 1800s these two were termed supplementary series. In 1896 Arthur Schuster stated his law: "If we subtract the frequency of the fundamental vibration from the convergence frequency of the principal series, we obtain the convergence frequency of the supplementary series". [5]
In molecular spectroscopy, a Jablonski diagram is a diagram that illustrates the electronic states and often the vibrational levels of a molecule, and also the transitions between them. The states are arranged vertically by energy and grouped horizontally by spin multiplicity . [ 1 ]
A wide variety of absorption band and line shapes exist, and the analysis of the band or line shape can be used to determine information about the system that causes it. In many cases it is convenient to assume that a narrow spectral line is a Lorentzian or Gaussian , depending respectively on the decay mechanism or temperature effects like ...
In physics, one thinks of a spectral line from two viewpoints. An emission line is formed when an atom or molecule makes a transition from a particular discrete energy level E 2 of an atom, to a lower energy level E 1, emitting a photon of a particular energy and wavelength. A spectrum of many such photons will show an emission spike at the ...