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Phase transitions (phase changes) that help describe polymorphism include polymorphic transitions as well as melting and vaporization transitions. According to IUPAC, a polymorphic transition is "A reversible transition of a solid crystalline phase at a certain temperature and pressure (the inversion point) to another phase of the same chemical composition with a different crystal structure."
These half-spaces are used to describe primitives that can be combined to get the final model. [7] Another approach decouples the detection of primitive shapes and the computation of the CSG tree that defines the final model. This approach exploits the ability of modern program synthesis tools to find a CSG tree with minimal complexity. [8]
[2] [3] [page needed] Pentagonal bipyramids are claimed to be promising coordination geometries for lanthanide -based single-molecule magnets , since they present no extradiagonal crystal field terms, therefore minimising spin mixing, and all of their diagonal terms are in first approximation protected from low-energy vibrations, minimising ...
Chemist Linus Pauling first developed the hybridisation theory in 1931 to explain the structure of simple molecules such as methane (CH 4) using atomic orbitals. [2] Pauling pointed out that a carbon atom forms four bonds by using one s and three p orbitals, so that "it might be inferred" that a carbon atom would form three bonds at right angles (using p orbitals) and a fourth weaker bond ...
Shape of water molecule showing that the real bond angle 104.5° deviates from the ideal sp 3 angle of 109.5°. In chemistry, Bent's rule describes and explains the relationship between the orbital hybridization and the electronegativities of substituents. [1] [2] The rule was stated by Henry A. Bent as follows: [2]
Women have written many textbooks and research papers in the field of X-ray crystallography. For many years Lonsdale edited the International Tables for Crystallography , which provide information on crystal lattices, symmetry, and space groups, as well as mathematical, physical and chemical data on structures.
Chemistry education is important because the field of chemistry is fundamental to our world. The universe is subject to the laws of chemistry, while human beings depend on the orderly progress of chemical reactions within their bodies. [2] Described as the central science, chemistry connects physical sciences with the life sciences and applied ...
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...