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Pivalic acid is prepared on a commercial scale by hydrocarboxylation of isobutene via the Koch reaction: (CH 3) 2 C=CH 2 + CO + H 2 O → (CH 3) 3 CCO 2 H. Such reactions require an acid catalyst such as hydrogen fluoride. tert-Butyl alcohol and isobutyl alcohol can also be used in place of isobutene. Globally, several million kilograms are ...
Standard acid catalysts are sulfuric acid or a mixture of BF 3 and HF. Although the use of acidic ionic liquids for the Koch reaction requires relatively high temperatures and pressures (8 MPa and 430 K in one 2006 study [ 9 ] ), acidic ionic solutions themselves can be reused with only a very slight decrease in yield, and the reactions can be ...
Industrially pinacolone is made by the hydrolysis of 4,4,5-trimethyl-1,3-dioxane, which is the product of isoprene and formaldehyde via the Prins reaction. It also is generated by ketonization of pivalic acid and acetic acid or acetone over metal oxide catalysts. 3-Methylbutanal is a starting material for 2,3-dimethyl-2-butene, which in turn is ...
pivalic acid trimethylacetic acid neopentanoic acid (CH 3) 3 CCOOH 3-hydroxypentanoic acid: β-hydroxyvaleric acid 3-hydroxyvaleric acid β-hydroxypentanoate:
In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted ) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction
It was first made by Aleksandr Butlerov in 1874 by reacting pivalic acid with phosphorus pentachloride. [ 2 ] Pivaloyl chloride is used as an input in the manufacture of some drugs, insecticides and herbicides.
3-Methylbutanoic acid (isovaleric acid) ... Pivalic acid; Propyl acetate; Tetrahydrofurfuryl alcohol; Valeric acid This page was last edited on 30 December 2021, at ...
Dichloroacetic acid (DCA), sometimes called bichloroacetic acid (BCA), is the organic compound with formula CHCl 2 CO 2 H. It is an analogue of acetic acid, in which 2 of the 3 hydrogen atoms of the methyl group have been replaced by chlorine atoms. Like the other chloroacetic acids, it has various practical applications.