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The absorption that occurs due to a transition between two states is referred to as an absorption line and a spectrum is typically composed of many lines. The frequencies at which absorption lines occur, as well as their relative intensities, primarily depend on the electronic and molecular structure of the sample.
The Fraunhofer lines are typical spectral absorption lines. Absorption lines are narrow regions of decreased intensity in a spectrum, which are the result of photons being absorbed as light passes from the source to the detector. In the Sun, Fraunhofer lines are a result of gas in the Sun's atmosphere and outer photosphere. These regions have ...
Spectral line shape or spectral line profile describes the form of an electromagnetic spectrum in the vicinity of a spectral line – a region of stronger or weaker intensity in the spectrum. Ideal line shapes include Lorentzian , Gaussian and Voigt functions, whose parameters are the line position, maximum height and half-width. [ 1 ]
A wide variety of absorption band and line shapes exist, and the analysis of the band or line shape can be used to determine information about the system that causes it. In many cases it is convenient to assume that a narrow spectral line is a Lorentzian or Gaussian , depending respectively on the decay mechanism or temperature effects like ...
Atomic absorption lines are observed in the solar spectrum and referred to as Fraunhofer lines after their discoverer. A comprehensive explanation of the hydrogen spectrum was an early success of quantum mechanics and explained the Lamb shift observed in the hydrogen spectrum, which further led to the development of quantum electrodynamics .
A diagram indicating the equivalent width corresponding to the absorption line, which is shown in red. The equivalent width of a spectral line is a measure of the area of the line on a plot of intensity versus wavelength in relation to underlying continuum level. It is found by forming a rectangle with a height equal to that of continuum ...
The broadened shapes of absorption lines in the optical spectrum depend on v rot sin(i), where i is the angle between the line of sight and the rotation axis, permitting the study of the rotational velocity's line-of-sight component v rot.
An absorption line is formed when an atom or molecule makes a transition from a lower, E 1, to a higher discrete energy state, E 2, with a photon being absorbed in the process. These absorbed photons generally come from background continuum radiation (the full spectrum of electromagnetic radiation) and a spectrum will show a drop in the ...